Simulated solar light-driven degradation of micropollutant in water by biochar-based metal-free catalyst: Regulation strategies for electronic structure and morphology engineering

Abstract

The biochar/h-BN/g-C3N4 (BNC) composite photocatalyst with a spherical sheet cluster structure, was successfully synthesized. Under simulated solar light irradiation, the photocatalytic degradation rate of reactive red 120 by BNC was 87.94 % within 90 min, corresponding to a 3.57-fold higher kinetic constant than that of g-C3N4. The band structure and electron transfer path in BNC were determined using characterizations and density functional theory (DFT) calculations, confirming a type II heterojunction forming. The attraction of h-BN to h+ by electrostatic interaction and biochar's capacity for both electron transfer and storage were confirmed. Doping of biochar was also found to enhance light absorption and provide O vacancy. The existence of piezoelectric effect assisted the movement of photogenerated carriers to the material surface. In the system, the main active oxidation species were h+ and ·O2–. By calculating optical characteristics, the practical activity of photocatalysts is evaluated. Results indicated that the optimal dosage of BNC was 0.5 g/L in the planar reactor, corresponding to an optical thickness of 2.61 calculated by the six-flux radiation absorption–scattering model (SFM). Biochar doping was found to enhance light absorption. A novel photocatalytic mechanism was proposed for promising matel-free BNC.