Simplified chemical chloramine decay model for water distribution systems

Abstract

This paper, presents a simplified model for predicting chemical chloramine loss in ultrapure water as a function of various measurable parameters, which otherwise requires the simulation of a complex mechanistic model involving the implementation of a number of ordinary differential equations (ODE), using specialised software. The complexity of the mechanistic model is evidenced by its lack of use outside chemical reaction modelling academics. We developed a simplified model as a single-line equation with eight fixed coefficients to predict the first-order decay coefficient. The developed model accurately predicts the first-order chloramine decay coefficient as a function of the water pH (7.5–8.5), chlorine-to-ammonia mass ratio (3.0–4.5), initial chloramine dose (1.5–5.0 mg/L), and alkalinity (up to 200 mg/L CaCO3) at 25 °C in ultrapure water samples. The user either has to input all the above mentioned water quality parameters or can evaluate the relative effect of water quality parameters individually or collectively, by using a relative model. The decay coefficient for temperature between 4 and 35 °C can be obtained by applying Arrhenius equation. To predict the chloramine profile, the initial chloramine concentration has to be decreased slightly (4% when pH < 7.8 to no adjustment at pH > 8.2) before the first order model is applied. Such a model will help in adding the effect of other parameters such as NOM, bromide, and microbiological decay in the future to facilitate easy adaptation by the water utilities.