Abstract

High-efficiency white emission is crucial to the design of energy-saving display and lighting panels, whereas solution-process feasibility is highly desirable for large area-size and cost-effective roll-to-roll manufacturing. In this study, we demonstrate highly-efficient, bright and chromaticity stable white organic light emitting diodes (OLEDs) with solution-processed single emissive layer. The resultant best white OLED shows excellent electroluminescence performance with forward-viewing external quantum efficiency, current efficiency and power efficiency of 22.7%, 48.8cdA−1 and 27.8lmW−1 at 100cdm−2, respectively, with a maximum luminance of 19,590cdm−2. Furthermore, we also observed an increment of 112% in the power efficiency, 86.9% in the current efficiency and a decrement of 39.2% in the external quantum efficiency at 100cdm−2 as the doping concentration of blue dye was increased from 10wt% to 25wt% in the devices. The better efficiency performance may be attributed to the effective exciton-confining device architecture and low-energy barrier for electrons to inject from the hole-blocking electron-transport layer to the host layer.

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