Abstract
The half esters, resulting from the Stobbe condensation of α-tetralone with succinic esters, on cyclization give the keto-ester “ethyl 3-ketoΔ 8-6,7-benzhydrindan-1-carboxylate”. This on Clemmensen reduction yields the corresponding αβ-unsaturated ester, from which 6,7-benzhydrindan-1-carboxylic acid was prepared by catalytic reduction and hydrolysis and this acid 6,7-benzhydrindan-1-hydroxymethyl ketone and its acetate were prepared.
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