Simple-Structured NIR-Absorbing Small-Molecule Acceptors with a Thiazolothiazole Core: Multiple Noncovalent Conformational Locks and D-A Effect for Efficient OSCs.

Abstract

Developing simple-structured and efficient near-infrared (NIR) absorbing small-molecule acceptors (SMAs) remains of great importance for commercial applications in organic solar cells (OSCs). Herein, we construct two novel thiazolothiazole-centered NIR-absorbing SMAs by alkoxy/alkylthio side chains (TTz3/TTz4) and multiple noncovalent conformational locks of S···N, S···O, and S···S. These conformational locks make both simple-structured SMAs exhibit an extended planar configuration and a red-shifted NIR absorption in comparison with the SMA with an alkyl side chain (TTz1). As expected, both SMAs show high-efficiency photovoltaic performance in the solution-processing OSCs using J71 as a donor. A higher power conversion efficiency of 8.76% with a low energy loss (0.57 eV) is obtained in the TTz3-based OSCs. It is the first report on the simple-structured and efficient NIR-absorbing SMAs, which have great potential applied in the semitransparent OSCs.