Abstract

The time-dependent formulation of Raman scattering is used to derive simple expressions for Raman progressions and combination bands. A procedure to calculate the harmonic potential parameters in the Franck-Condon region and the homogeneous damping constant is presented. It is shown that all Raman bands can be evaluated by using a simple recursion relation if the short-time representation for the correlation function is adequate. A numerical application to the resonance Raman spectrum of Cs 3[ Re 2 OCl 10] is described.

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