Abstract

The model able to directly connect micro parameters of a liquid (intermolecular potentials of interacting molecules) with macro parameters P, V, T is described. Thus the transition is formulated for the first time similar to the usual one connecting kinetic representations of a gas or a liquid as scores of chaotically moving particles with macroscopic characteristics of an ensemble. The way is specified to obtain potential parameters of particle interaction in the model by basing on the detailed description of potentials of intermolecular interactions in a real liquid media.

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