Abstract
MODERN kinetic techniques for the study of chemical relaxation use step functions to perturb chemical equilibrium1. The response from the chemical system, measured optically for instance, usually consists of an exponential decay function. Let us assume a signal S, containing a multiple step relaxation function, illustration where An are the amplitudes, τn the relaxation times, t the time and N(t) the noise (shot noise from a multiplier, for example) associated with the signal. For simplicity I omit relaxational components of higher order in S and consider the case n≤2. More complicated relaxation functions can be analysed in the same way. Open image in new window
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