Abstract
AbstractThe changes of the free energy of activation δ∆G≠exp and the activation entropy δ∆S≠ in the framework of the isokinetic relationship δ∆G≠exp versus (Tiso − Texp) δ∆S≠ were explored quantitatively to predict the isokinetic temperature Tiso for the aromatic nucleophilic substitution reactions in solution.
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