Abstract
The late transition metal ions from Cr + to Zn + react with i-C 3H 7NCO ( 1) to form M(HNCO) + and M(C 3H 6) + complexes. Secondary reactions of both ions with 1 afford MC 4H 7NO + ions. While for Cr +, Mn +, and Zn + these products correspond to adduct complexes M( i-C 3H 7NCO) +, for Fe +-Cu +, at least partly, isomeric M(HNCO)(C 3H 6) + complexes are formed.
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