Simple and Fast Microwave-Assisted Synthesis Methods of Nanocrystalline TiO2 and rGO Materials for Low-Cost Metal-Free DSSC Applications.

Abstract

Nanocrystalline TiO2 and reduced graphene oxide (rGO) materials have been synthesized by a simple and low-cost microwave-assisted hydrothermal method and applied in dye-sensitized solar cells (DSSCs) as photoactive and metal-free counter electrodes, respectively. Different TiO2 nanocrystalline materials have been synthesized via the acid hydrolysis sol–gel method, followed by microwave hydrothermal treatment at 210 °C and 300 psi and at different microwave irradiation times (20, 30, 45, and 60 min) instead of the usual hydrothermal time of 12 h. The properties of the produced mesoporous nanocrystalline TiO2 are investigated in terms of their morphology, crystal structure, optical properties, and surface area behavior using relevant characterization techniques. Maximum specific surface area values (SBET) of 97.77 and 100.7 m2 g–1 are measured for TiO2, with the average crystallite sizes of 18.6 and 17.5 nm, at microwave irradiation times of 30 and 45 min, respectively. Different rGO samples have been prepared by the modified Hummers method, followed by microwave-assisted reduction at a temperature of 200 °C and pressure of 300 psi at different microwave irradiation times (3, 17, and 25 min). The physicochemical properties of the different rGO samples in terms of morphology, crystallization, and optical properties are characterized by TEM, XRD, and Raman spectroscopic analysis. The current density Jsc of the fabricated DSSCs based on TiO2 as the photoelectrode and rGO as the counter electrode compared with DSSCs based on Pt as the counter electrode is found to be 11.25 and 9.28 mA cm–2, respectively. Although the overall power efficiency of the fabricated DSSCs based on rGO as the counter electrode is lower than that based on the Pt electrode, the former still exhibits promising prospects for replacing Pt with low-cost metal-free carbon-based DSSCs.