Abstract

Reactions of hydrosilanes with 1-hexyne catalyzed by Co 2 Rh 2 (CO) 12 and Rh 4 (CO) 12 at 25 o C and atmospheric pressure-150 psi of carbon monoxide give (Z)-1-silyl-2-formyl-1-hexenes, which are the products of «silylformylation», and/or (E)-1-silyl-1-hexenes

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