Abstract
A base-mediated silylation reaction leading to benzyl silanes has been developed. Under transition-metal and solvent free conditions, the silylation of a wide array of p-quinone methides is achieved using a Cs2CO3 catalyst in yields up to 96%. Carboxylation of the as-obtained organosilane with gaseous CO2 provides a new synthetic protocol for the preparation of carboxylic acid.
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