Abstract
In the presence of lithium and in tetrahydrofuran as solvent, trimethylchlorisilane reacts with tetralin to give two new compounds, (I) and (II). The latter when refluxed with acetic acid leads to a new monosilylated olefin (III). The study of the desilylation mechanism leads to envisage an isomerization of allyl- into vinyl-silane.
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