Abstract
Organocuprate addition reactions on methyl-bis(trimethylsilyl)aminomethyl-propiolate lead to the formation of a Z-vinyl cuprate with a high stereoselectivity. Upon reaction of acid chloride, pyrroles are formed by a spontaneous intramolecular cyclisation of the intermediate Z-silylamino enone. Various functional substituted pyrroles can be obtained in one step by this route.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
