Abstract

AbstractSilver rubidium iodide (RbAg4I5) is a unique solid electrolyte because of its extremely high conductivity which has an almost negligible electronic contribution. This characteristic makes RbAg4I5 a very promising electrolyte for the development of high‐power solid‐state batteries. Consequently, a considerable amount of work has been carried out on this compound since its discovery in 1967. In the first part of this paper the physicochemical and electrochemical properties of this electrolyte are reviewed, and then the characteristics and performances of RbAg4I5 solid‐state cells are discussed.

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