Abstract
[reaction: see text] Highly substituted bicyclo[3.2.1]octadiene building blocks are easily prepared from tetrachloro- or tetrabromocyclopropene through reaction with cyclic dienes. These polyhalogenated derivatives can serve as precursors to a variety of functionalized bridged bicyclic compounds. Herein, we report on the generation and reaction of electrophilic species with silver ion.
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