Silver-platinum bimetallic nanoparticles as heterogeneous persulfate activator for the oxidation of malachite green

Abstract

Fabrication of noble metal nanoparticles by using green chemical method with plant extract as reducing agent to the in situ oxidation toxic water contaminants have been the subject of various investigators due to their enhanced catalytic efficiencies. This paper describes the extraction of caffeic acid from Artemisia herba-alba aqueous extract, and preparation of silver (Ag), platinum (Pt), and silver-platinum (Ag-Pt) nanoparticles with caffeic acid as a reducing and capping agent. The as-prepared Ag-Pt NPs was used as a heterogeneous activator of persulphate (K2S2O8) for the in situ chemical oxidation of malachite green (MG). The Ag-Pt NPs shows no surface Plasmon resonance absorption band. The malachite green dye was completely decolorized in presence of Ag-Pt/K2S2O8 system. SO4-• and HO• radicals generated by the cleavage of S2O82- peroxide activation with Ag-Pt were responsible for the MG decolorization as well as mineralization. The Ag-Pt NPs acted as a sacrificial electron donor. The Ag-Pt NPs were characterized by using conventional techniques such as, UV–visible, FTIR, SEM, TEM, EDX, XPS, and XRD spectroscopic methods.