Abstract

One-dimensional metal nanowires, with novel functionalities like electrical conductivity, optical transparency and high mechanical stiffness, have attracted widespread interest for use in applications such as transparent electrodes in optoelectronic devices and active components in nanoelectronics and nanophotonics. In particular, silver nanowires (AgNWs) have been widely researched owing to the superlative thermal and electrical conductivity of bulk silver. Herein, we present a detailed review of the synthesis of AgNWs and their utilization in fabricating improved transparent conducting electrodes (TCE). We discuss a range of AgNW synthesis protocols, including template assisted and wet chemical techniques, and their ability to control the morphology of the synthesized nanowires. Furthermore, the use of scalable and cost-effective solution deposition methods to fabricate AgNW based TCE, along with the numerous treatments used for enhancing their optoelectronic properties, are also discussed.

Highlights

  • One-dimensional (1D) metal nanomaterials have attracted widespread research interest due to their unique electrical, magnetic, optical, thermal and catalytic properties

  • We discussed the various Ag nanowires (AgNWs) synthesis protocols and strategies used for fabricating transparent conducting electrodes (TCE) with improved optoelectronic properties

  • While AgNW based TCE have several advantages including scalable solution based processing capability, low sheet resistance, high conductivity, low surface roughness and mechanical flexibility and stretchability, there are still some issues that need to be resolved; for example, the non-uniform distribution of the AgNW network obtained during solution based deposition can lead to localized joule heating, which can degrade optoelectronic performance [266]

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Summary

Introduction

One-dimensional (1D) metal nanomaterials have attracted widespread research interest due to their unique electrical, magnetic, optical, thermal and catalytic properties. Nanomaterials 2021, 11, 693 high fabrication cost and brittle nature, which hinders its applicability for use in n generation flexible optoelectronic devices like smart windows [17,18], electronic s [19], smart clothes [20], wearable heaters [21,22], foldable displays [23,24,25,26], compliant s cells [27] and flexible display panels [28] These devices require TCE that fulfill cer criteria, including solution-based low cost processing capability, excellent oofp50toelectr properties, mechanical compliance and chemical stability.

AgNW Synthesis
Template Methods
Hard Template Method
Chemical Methods
Polyol Method
Key Findings
AgNW Based Transparent Conductive Electrodes
Transparent Conducting Electrode Fabrication Methods
Spray Coating
Spin Coating
Doctor Blade Coating
Roll-to-Roll Slot Die Coating
Dip-Coating
Printing Techniques
TCE Enhancement Method
Thermal Annealing
Cold Welding
Joule Heating and Electro-Deposition Methods
Light Induced Welding
Method Spray coating Spin coating
Findings
Conclusions and Future Outlooks
Full Text
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