Abstract
A radical trifluoromethylarylation of <i>N</i>-arylacrylamides with in situ generated [AgCF<sub>3</sub>] species from Me<sub>3</sub>SiCF<sub>3</sub> and AgF in DMF is established through a tandem radical addition and C–H activation pathway. It provided a concise method to prepare 21 examples of CF<sub>3</sub>-containing oxindoles within four hours.
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