Silver-Mediated Formation of a Cofacial Porphyrin Dimer with the Ability to Intercalate Aromatic Molecules

Abstract

Gastfreundlich: Die Komplexierung von AgI-Ionen durch den Zn-Porphyrin-Liganden L mit vier 2,2′-Bipyridyl-Gruppen ergibt den dimeren Komplex [Ag4L2]4+. Der Abstand zwischen den beiden Zn-Porphyrin-Gruppen ist ideal für die Interkalation aromatischer Moleküle unter Bildung von π-π-Wechselwirkungen, und daher wirkt [Ag4L2]4+ als hervorragender Rezeptor für π-elektronenarme Gastspezies. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.