Abstract
AbstractA direct synthesis method of efficient and mild water‐resistant organoindium reagents and their cross‐coupling reactions with aryl iodide by palladium‐catalyzed was described. At room temperature, organic indium reagents were mediated by AgI, and water‐tolerant alkyl indium reagents were directly and efficiently synthesized. The cross‐coupling reaction of organic indium reagents with various aryl halides could perform smoothly with palladium catalysis. The expected products were obtained in moderate to good yields, and the best yield can reach 99 %. These reactions are promising for their high reactivity, broad applicability, and functional group tolerance.
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