Silver-Doped BaSrTiO₃ Nanocomposite: Synthesis, Characterization, Antibacterial and Photocatalytic Activities.

Abstract

In this research, strontium titanate (SrTiO₃), barium titanate (BaTiO₃), barium strontium titanate (BaSrTiO₃), and Ag-doped BaSrTiO₃ nanocomposites with different Ag contents were fabricated using the sol-gel chemical route. The prepared samples were characterized by several techniques including scanning electron microscopy (SEM), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), differential reflectance spectroscopy (DRS), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), inductively coupled plasma spectroscopy (ICP), and Brunauer-Emmett-Teller (BET) measurement. The EDS results indicated that the synthesized nanoparticles had a cube perovskite-like structure. The EDS and ICP results revealed that Ag was doped into the Ba0.5Sr0.5TiO₃ structure. The SEM and TEM images demonstrated that the particle size of 15 mol% Ag-doped Ba0.5Sr0.5TiO₃ was smaller than that of pure Ba0.5Sr0.5TiO₃ as confirmed by surface area results. The photocatalytic properties of undoped titanate samples and Ag-doped Ba0.5Sr0.5TiO₃ were studied by the photodecomposition of Eosin yellowish (EY) and methylene blue (MB) dyes. The results illustrated that the photodegradation efficiency of the Ag-doped Ba0.5Sr0.5TiO₃ was far higher than the undoped titanate sample, and the optimum Ag doping was 15 mol%. The antibacterial activities of pure Ba0.5Sr0.5TiO₃ and Ag-doped Ba0.5Sr0.5Ti0₃ were studied against Staphylococcus aureus as Gram-positive (+) and Pseudomonas aeruginosa and Escherichia coli as Gram-negative (-) bacteria. In comparison with the bare Ba0.5Sr0.5TiO₃ nanoparticles, the Ag-doped sample showed a significant enhancement in antibacterial activities against both Gram-negative and Gram-positive bacterial strains.