Abstract

AbstractThe silver carbonate‐catalyzed direct C${{_{sp{^{2}}}}}$H phosphorylation of indoles in the presence of magnesium nitrate is described. The reaction affords selectively phosphonoindoles in moderate to good yields through a radical process. This protocol provides an efficient and general method for the preparation of 2‐ and 3‐phosphorylated indoles.magnified image

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