Abstract
AbstractDioxazolones and isocyanides are useful synthetic building blocks, and have attracted significant attention from researchers. However, the silver‐catalyzed nitrene transfer reaction of dioxazolones has not been investigated to date. Herein, a silver‐catalyzed acyl nitrene transfer reaction involving dioxazolones, isocyanides, and water was realized in the presence of Ag2O to afford a series of N‐acylureas in moderate to good yields.
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