Abstract
Several isopropylsilanes including tetraisopropylsilane have been obtained by the reaction of chloro- or fluoro-silanes with isopropyllithium. Their AB 6 proton NMR spectra have been recorded and analyzed. The reaction between triisopropylfluorosilane and isopropyllithium in ether gives triisopropyl(3-methylbutyl)silane as the main product. In petroleum ether as solvent, however, tetraisopropylsilane together with triisopropylsilane is formed.
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