Siliceous deposition in limestone-marl alternations of the Yangtze Carbonate platform during the Permian Chert Event

Abstract

During the Permian Chert Event (PCE), limestone-marl alternations (LMAs), contemporaneously developing in the Yangtze region with chert-mudstone alternations, differed from typical LMAs by their enrichment in authigenic siliceous components (quartziferous components and Mg-phyllosilicates). However, the factors driving the transition from distal chert deposits to proximal siliceous-rich carbonate deposits remain unclear, and the genesis of authigenic siliceous components is puzzling. Resolving these issues could provide a deeper understanding of the paleoclimate and paleoenvironment during the PCE. Optical and SEM observations and geochemical analyses revealed that Si4+, derived from seawater, silica-secreting organisms, and terrigenous clasts, precipitated as authigenic quartziferous components under relatively acidic conditions, while it precipitated as Mg-phyllosilicates through reverse weathering by combining with the dissolved high-Mg calcites under relatively alkaline conditions. Through the facies division of LMAs, its variations describe relative and short-term sea-level fluctuations in the Yangtze Carbonate Platform (YCP). By integrating tendency comparisons and time series analyses of sea level fluctuations, continental weathering intensity, authigenic siliceous content, and relative proportions of quartz vs. Mg-phyllosilicates, four proxies exhibit covariation and similar astronomical signals, indicating that the high sea level period of the YCP, corresponding to intensified continental weathering, favored the deposition of authigenic siliceous components and reverse weathering. Because the facies variations encompass short eccentricity, obliquity, and precession cycles, sea level fluctuations are considered to have been influenced by Gondwana glaciation P3. The seawater in the continental shelf cooled and became rich in silica and nutrients under the effect of upwelling. Interglacial periods may trigger high sea levels and intensified continental weathering in the YCP, facilitating the influx of Si-rich eutrophic seawater and stimulating biological silica secretion by radiolarians. However, the direct precipitation of activated silica resulted in weakened reverse weathering. Consequently, the lithological transformation from distal to proximal areas during the PCE was attributed to differences in silica-secreting organism abundance, upwelling intensity, biological pump activity, reverse weathering intensity, OM abundance, pH conditions, and seawater temperature between the continental shelf and carbonate platform.