Silica Properties/Rubber Performance Correlation. Carbon Black-Filled Rubber Compounds

Abstract

Abstract The effectiveness of predicting rubber performance based on measured silica physical properties in silica- and carbon black-filled compounds is presented for three rubber formulations: an off-the-road tire tread, a wire coat stock and a V-belt. Correlation and regression analyses were performed using SAS software for sixteen physical properties of thirteen precipitated silicas, and sixteen rubber compound performance characteristics of the three compounds. Silica physical properties studied include various measurements of surface area and structure, particle size, pH and impurities. Rubber performance characteristics studied include cure properties and physical properties such as stress/strain, tear strength, cut growth resistance, abrasion resistance and heat build-up. The present study confirms that silica surface area is the single best predictor of the effect that varying silica physical properties have on the physical performance of cured, carbon black-filled rubber compounds containing precipitated silica. Silica structure, as measured by DBP absorption and nitrogen or mercury pore volume, is a secondary predictor of certain rubber physical properties. The confidence limits of the predictions is dependent upon the concentration of precipitated silica used in the carbon black-filled rubber compound.