Silica Nanoparticles Modified with Trithiocyanuric Acid as a Potential Adsorbent for Removal of Ag+ from Aqueous Solutions

Abstract

Surface modification of the silica nanoparticles was performed using trithiocyanuric acid (TCA-SNPs) so as to enhance the adsorption of Ag+ from aqueous solutions. The surface modification to the adsorbent was characterized by Fourier transform infrared spectroscopy, transmission electron microscope, and X-ray photoelectron spectroscopy. The Ag+ adsorption capacity was found to increase with increase in the solution pH, with the optimal pH being 5.0. The Ag+ adsorption isotherm was generated at 25 °C at the optimal solution pH and the maximum adsorption capacity was found to be 80 mg/g, significantly higher than the adsorption capacity reported for other adsorbents in literature. The increase in adsorption capacity was attributed to the presence of thiol groups on the surface of the modified adsorbents. Additionally, the adsorption kinetics was estimated at 25 °C, which indicated very high rates of adsorption initially, with rapid reduction in rate of adsorption with time. Both adsorption isotherms as well as the adsorption kinetics were modeled with popular models. The adsorption isotherm was found to match with the Langmuir model while the adsorption kinetics was found to match with the pseudo-second-order kinetic model. The adsorption-desorption cycles indicate the TCA-SNPs to be stable adsorption performance and retain high adsorption efficiency ensuring commercial adoption. A relatively low adsorption of other ions such as Mn2+, Cu2+, Ni2+, Co3+ as compared to Ag+ was ensured.