Abstract

We present rich IR spectra of solid samples of C 60 and its derivatives. Most of the IR lines are identified as the activated silent modes of the C 60 or second-order combination modes. The method of preparation of a complex of C 60 and chloro(triphenyl-phosphine) gold grown from toluene solution is described. Basic physical properties, in particular IR transmission of the single crystals of the complex, are studied as a function of temperature. Anomalies in the temperature dependences of the linewidths, their frequencies and intensities are observed and discussed.

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