Abstract

2D/2D van der Waals Heterostructures In article number 2100296, Shi-Zhang Qiao and co-workers present a ReS2/In2ZnS4 2D/2D van der Waals hetero-junction (vdWH) that exhibits a highly-promoted visible-light photocatalytic H2-production rate of 2515 mmol h−1 g−1. This is 2266% times that for In2ZnS4. The outstanding performance is attributed to efficient interfacial electron-hole dissociation/transportation, and substantial atomic-level S active sites on ReS2. Results will be of immediate benefit in the rational design/synthesis of vdWHs for solar hydrogen generation.

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