Abstract
We report a new spectroscopic detection scheme for molecular oxygen that achieves roughly two orders of magnitude higher sensitivity for fully rotationally resolved spectra than the current state of the art. Two-color (2 + 1') resonance-enhanced multiphoton ionization (REMPI) via the 3d Rydberg complex yields state-selective spectra with signal comparable to the intense but diffuse C 3sσ 3Πg ← X 3Σg- (2 + 1) REMPI bands without significant saturation or broadening. The resulting increase in sensitivity permitted observation of the very weak 3dπ 1Δ2 ← X 3Σg- transitions and is independent of the intermediate state. This advance in ionization efficiency and quantum state-selective sensitivity for O2 promises to aid physical and chemical studies across a wide variety of fields.
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