Abstract
The triazinone herbicides metamitron and metribuzin are degraded by desamination. After a derivatization step with ethereal diazomethane solution, different structures of the metabolites were determined by GC/MS. The assumption that this is based on a ketoenol-tautomery was confirmed by GC/FTIR and 1H-NMR spectroscopy. This fact has to be considered for carrying out definite metabolite identification.
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