Abstract
The electronic absorption spectra of sigma complexes of the Meisenheimer type, viz., the anions of potassium salts of 4H-5-nitro-4-acetonylpyrimidines, were investigated. The 5-nitropyrimidine molecule and its sigma complex involving the 4 position were subjected to quantum-chemical calculation by the simple MO LCAO method. It is shown that it is expedient to use the Forster-Dewar-Knott rule for the study of the electronic spectra of the indicated sigma complexes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
