Abstract
AbstractIron tailings remain the environment‐damaging waste from the iron ore, and high porosity porous ceramics are an attractive material to “turn waste into treasure.” To improve the thermal conductivity, porous ceramics with high silicon carbide content have been prepared by carbothermal reduction sintering process using argillaceous fine‐grained iron tailings with high silica content. The carbothermal reduction reaction mechanism and the components and properties of samples in sintering process are investigated. The results show that reaction components in the tailings are mainly SiO2 and Fe2O3 and liquid phase is generated rapidly between 1200°C and 1300°C, producing foaming effect and significantly improving the porosity. Moreover carbothermal reduction of SiO2 occurs above 1300°C. After sintering at 1600°C for 2 hours, the apparent porosity and thermal conductivity of porous iron tailing ceramics are 81.1% and 0.58 W/(m·K), respectively. Compared with the ordinary porous iron tailing ceramics with the same porosity, the thermal conductivity of those herein is increased by 6.6 times. This study is instructive for the development of low‐cost preparation technology of phase change material carriers.
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