Abstract
The reaction of trisilirene 1 with propylene sulfide or elemental sulfur produced Si3S-bicyclo[1.1.0]butane 2, which underwent Si–Si insertion of a second S atom forming Si3S2-bicyclo[1.1.1]pentane 3. Analogous reactions of 1 with elemental Se or Te resulted in the formation of heavier analogues of 2, namely, Si3Se-bicyclo[1.1.0]butane 4 and Si3Te-bicyclo[1.1.0]butane 5. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. GRAPHICAL ABSTRACT
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