Abstract
Departures from Gaussian lineshape in Si(Li) spectra arise from the radiative Auger effect, the intrinsic Lorentzian shape of X-ray emission lines, double ionization and spectator vacancy satellites, electron escape from the detector and carrier diffusion within it, and from imperfections in the charge collection process. Rather than describe empirically the tailing function that arises collectively from these effects, we prefer to incorporate those that are fundamental in nature into the lineshape model, and to reserve empirical description for the minority component that is truly an artefact reflecting imperfections in the device. A useful alternative to such a lineshape description is a weighting scheme that de-emphasises the tails of intense peaks in a least-squares fitting process.
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More From: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
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