Abstract
Silicon thin film with both remarkable stability and graphenelike properties attract many research interests in materials science and condensed matter physics. In this paper, two new two-dimensional silicon allotropes (Si-Cmma and Si-Pmma) with excellent energetic stability and positive dynamical stability are proposed and investigated by first-principles calculations. Si-Pmma possesses the energy of about 203 meV/atom lower than that of silicene and it is a normal metallic phase. Si-Cmma is of about 198 meV/atom lower than silicene in energy and it is confirmed to be a nodal loop semimetallic material. Symmetry analysis reveals that the nodal loop in Si-Cmma is protected by the glide mirror and it belongs to class AI $+$ R of Altland-Zirnbauer symmetry classes. A further three-band $k\ifmmode\cdot\else\textperiodcentered\fi{}\mathrm{p}$ model is constructed to understand the formation of the nodal loop and its strong anisotropy.
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