Abstract
Use of the trichloroacetimidate method for the synthesis of cerebroside has reduced the number of reaction steps and increased the yields. The key step is the reaction of the 1-O-unprotected D,L-ceramides with a trichloroacetimidate to give the D-glucocerebrosides DL-1 and DD-1, which can be quantitatively deblocked to produce DL-2 and DD-2 (natural product).
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