Abstract
Equilibrium constants for proton transfer complex formation between 2,4-dinitrophenol and aliphatic amines have been measured at 25°C for benzene solvents containing small amounts of dimethylformamide, acetonitrile, ethyl acetate, or dioxane. The results support the concept of amine-solvent hydrogen bond formation, which increases the reactivity of the amines as bases. Such hydrogen bonds increase amine basicity more than would the inductive effects of an added alkyl group.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
