Abstract
Laser-induced fluorescence excitation spectra observed using the D 1 Σ 0 + ← X 1 Σ 0 + transition were used to determine the D 1 Σ 0 + -state potential in ZnNe, ZnAr and ZnKr. The complexes were produced in a free-jet expansion beam and excited with a dye-laser beam from the ground to the excited state. Analysis of the unstructured free ← bound profiles yielded information on the short-range repulsive part of the D 1 Σ 0 + -state potential. Ab initio calculations of the potential energy curves for the ground and excites states as well as for electronic transition dipole moments of the studied transition were performed taking scalar relativistic and spin–orbit effects into account.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
