Abstract

Measurements of the low frequency limiting value of the relative permittivity e can provide useful information about molecular interactions in liquids and gases. In particular, the value of e for a solution of a polar solute in a nonpolar solvent may be measured as a function of concentration and temperature to study association in the liquid state. This technique is extensively used to examine hydrogenbonding interactions and may be used to study weak complexes involving charge transfer effects.1,2

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