Abstract

The atomic structure of polymorphic zirconia powders doped with 6 mol.% yttria prepared by controlled hydrolysis of alkoxides has been studied by X-ray absorption spectroscopy. The short-range orders before and after heat treatment have been compared. The crystallization and incorporation of the yttrium atoms into the network have been monitored. Rietveld analysis of X-ray diffraction data has been used to determine the relative amounts of crystalline phases present in the sample.

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