Abstract
We calculate and present the shifts that are induced by predissociation of the band origins in the A2Σ+–X2Π system of the hydroxyl radical 16OH, using a sum rule method in which the projection of the predissociating interaction onto a complete set of states is replaced by a single linear response. We present also the corresponding shifts for the isotopomers 18OH, 16OD and 18OD.
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