Shift of major driver for chemical weathering from the natural control to human dominance since 1980s in the Taihu watershed, China.

Abstract

Anthropogenic acidification has become a concerned problem in the Taihu region; however, how it affected the regional weathering rate, especially at the different sub-watershed levels has hardly been studied. To reveal the impact of human activities on watershed weathering and water chemistry in Taihu sub-watersheds, historical water chemistry data (1950s-1970s) and recent water samples (2018-2021) of the local river systems, as well as sediment samples of Taihu lake were collected and analyzed, and a linear addition mass balance method was used to determine the weathering rate at the sub-watershed level. The results indicated that, compared with 60years ago, the current weathering rate of carbonates and silicates in the Taoge water system (TG) was the highest, reaching 67.2 and 11.4 t·km-2·a-1, increasing by 4.1 and 2.7-folds, respectively; and meanwhile the carbonate and silicate weathering rates increased by 3.1 and 4.9-folds in the Nanhe water system (NH), and 5.2 and 3.4-folds in the Tiaoxi water system (TX), respectively. The increasing rate was significantly correlated to the atmospheric SO2 concentration in different sub-watersheds and was affected by the sub-watershed lithology, e.g., TX had a higher increase rate of silicate weathering due to the wider distribution of silicates in this sub-watershed than the other two. The sediment evidence of Na/K and Ca/Al on the profile in different lake parts, which was influenced by different influx river systems, confirmed that the overall intensity of watershed weathering was higher in TG than in the TX sub-watershed and was higher in the recent decade than 50-60years ago. The accelerated weathering rate was found to present a definite consistency with the social and economic development in the watershed. Combined analyses of the accelerated weathering rate in the watershed and sedimentation evidence indicated that the major driving force for the watershed weathering has shifted from carbonic acid under the natural condition to human-induced sulfuric acid since 1980s.