Abstract
Interfacial chemistry earned huge interest due to its wide range of application in various fundamental researches. Shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) can overcome the morphology and material generality problems of surface-enhanced Raman spectroscopy, thus providing ultrasensitive and fingerprint structural information. This article provides a brief overview of the SHINERS technique and its applications at electrochemical interfaces. First, we simply introduce the SHINERS technique development history. And then further describe several representative applications of electrochemical SHINERS (EC-SHINERS) on electrode surfaces, including the molecular adsorption, corrosion resistance, catalytic reactions and other applications studies at polycrystalline and single crystal electrode surfaces. Finally, we summarize the recent developments and outlook for future developments of SHINERS and shell-isolated mode.
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