Abstract

A strip of carbon fabric (CF) electrode modified with multiwalled carbon nanotubes and subsequently fructose dehydrogenase (FDH) showed an oxidation current density of ∼11mAcm−2 in stirred 200mM fructose solution. Obtaining a sufficient dispersion of the nanotubes during its modification was found to be critical to ensure such a performance of the FDH anode. For use with this anode, a CF strip modified with ketjenblack (KB) and bilirubin oxidase (BOD) served as a gas-diffusion cathode for the reduction of O2 from air at a current density of ∼2mAcm−2. The FDH-modified CF strip and the BOD-modified CF strip were stacked with an agarose film that retained an electrolyte solution and fuel (fructose) to construct a totally flexible sheet-shaped biofuel cell. This assembly allowed bending of 44° without affecting the maximum output power density, 550μWcm−2 obtained at 0.4V.

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