Shear viscosity and dielectric relaxanon time of dibutyl phthalate down to glass transition temperature.

Abstract

We studied the shear viscosity and the main dielectric relaxation time of dibutyl phthalate from 97°C down to −96°C (near its glass transition temperature Tg). A visco penetrometer and a dielectric spectrometer built in our laboratories allowed us to obtain experimental data in the ranges 10-10 9 Pa.s for viscosity and 1 mHz–2 MHz for dielectric relaxation time. All these data and those of different authors give viscosity and dielectric relaxation time versus temperature on twelve decades; they are well fitted by the Cohen and Grest relation. These fits obtained on a large temperature range show that there is a strong correlation between viscosity and dielectric relaxation time. Furthermore it appears that the dielectric relaxation time distribution is broadening in the vicinity of Tg.