Abstract
A derivative neopolarogram is the peaked curve that is generated by semidifferentiation of the current that flows in response to an imposed ramp signal on a stationary electrode. Theory is presented that describes the shapes of such curves for both reversible and irreversible electrode processes at planar and spherical electrodes. Because the shapes are much more complicated in the spherical case, a procedure is discussed for correcting derivative neopolarograms obtained with spherical electrodes.
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