Shape morphology of dipolar domains in planar and spherical monolayers.

Abstract

We present a continuum theory for predicting the equilibrium shape and size of dipolar domains formed during liquid-liquid phase coexistence in planar and spherical monolayers. Our main objective is to assess the impact of the monolayer surface curvature on domain morphology. Following previous investigators, we base our analysis around minimizing the free energy, with contributions from line tension and electrostatic dipolar repulsions. Assuming a monodisperse system of circularly symmetric domains, we calculate self-energies and interaction energies for planar and spherical monolayers and determine the equilibrium domain size from the energy minima. We subsequently evaluate the stability of the circularly symmetric domain shapes to an arbitrary, circumferential distortion of the perimeter via a linear stability analysis. We find that the surface curvature generally promotes the formation of smaller, circularly symmetric domains instead of larger, elongated domains. We rationalize these results by examining the effect of the curvature on the intra- and inter-domain dipolar repulsions. We then present a phase diagram of domain shape morphologies, parameterized in terms of the domain area fraction and the monolayer curvature. For typical domain dimensions of 1-30 µm, our theoretical results are relevant to monolayers (and possibly also bilayers) in liquid-liquid phase coexistence with radii of curvature of 1-100 µm.